well-timed: coming at just the right moment, or well-suited to the occasion at hand
The word joins "good" or "well" to the ordinary Greek word for a fitting or decisive time (καιρός), giving the plain sense "having a good moment." It describes something that lands at exactly the right time, or that suits the occasion perfectly. It appears only twice in the New Testament, and in both places it is the setting, not the word itself, that supplies the emotional color.
In Mark's account, it marks "an opportune day": Herod's birthday banquet finally handed Herodias the chance she had been waiting for to have John the Baptist killed. The moment is "well-timed" for a wicked plan, which gives the word a sharply ironic edge. In Hebrews the feeling is the opposite: God's help is "well-timed," arriving at exactly the moment of need for the person who comes to him.