to pay a tithe of something: to hand over a tenth of one's produce or income as a sacred due
This is the everyday direction of the word, the one on the lips of the person doing the giving. It describes handing over a tenth of what you have grown or earned, offered to God as an obligation rather than a free gift. In the Gospels it is what a careful, observant Jew does with the crops from his fields, right down to the small herbs in his garden.
When Jesus faults the religious leaders for tithing mint, dill, and cumin while neglecting justice, mercy, and faithfulness, the charge is not that they tithe but that they have lost all sense of proportion. He tells them the small duties should be done without leaving the weighty ones undone. In the parable of the Pharisee and the tax collector the same word carries a boast: the Pharisee gives a tenth of everything he acquires, going beyond what the law strictly required.
In every one of these places the word points the same way. The person named is the one paying, and the tenth flows outward from his own hand.